If you're intending to work in Singapore, a MSc from NTU is great. However, a lot of times, getting a good employment here also depends on your good luck and good connections.
So while you're in school in NTU, network as much as possible, present papers in conferences if you can, and even do project work if you could cope, and get to know the work/life culture here. Most importantly, come with an open mind. When you do all these, you get a good headstart of corporate Singapore.